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Friday, July 17, 2020 | History

2 edition of Thermal and enzymatic degradation of raspberry anthocyanins found in the catalog.

Thermal and enzymatic degradation of raspberry anthocyanins

George Vasilios Daravingas

Thermal and enzymatic degradation of raspberry anthocyanins

by George Vasilios Daravingas

  • 67 Want to read
  • 15 Currently reading

Published .
Written in English

    Subjects:
  • Raspberries.,
  • Anthocyanins.

  • Edition Notes

    Statementby George Vasilios Daravingas.
    The Physical Object
    Pagination106 leaves, bound :
    Number of Pages106
    ID Numbers
    Open LibraryOL14289966M

    The results show that the anthocyanin in wild blueberry fruit is instable to heat, the degradation of anthocyanin in wild blueberry fruit is followed first-order reaction kinetics, and the thermal degradation activation energy of anthocyanin in wild blueberry fruit is kJ/mol, the k 0 is The theoretical value and experimental. The anti-oxidation activity, thermal degradation, and photo degradation of PSPAE were examined, in response to processing and storage conditions such as pH value, temperature, solvent, and time, by measuring anthocyanin content, degradation index (DI), chromatic aberration (ΔE), T 1/2, and reaction rate constant (k). The pH value is a more.

    Anthocyanin discoloration in Solanaceae is therefore more likely due to a change in the balance between anthocyanin biosynthesis and degradation, i.e., a decrease or termination of anthocyanin biosynthesis and/or an increase of anthocyanin degradation. There are various enzymatic and non-enzymatic factors that affect the stability and.   The degradation kinetics of purified anthocyanins followed a first-order reaction with reaction rate constants (k values) of – min–1, an activation energy of kJ/mol, thermal death times (D values) of – min, and a z value of .

    The aim of this study was prevention of thermal degradation of blackberry juice anthocyanins through sugar addition. Blackberry juice samples were prepared without and with addition of 10% of different sugars (sucrose, fructose, glucose and trehalose), and heated at 50, 70 and 90 °C for 1 and 2 h. Drying was proposed for obtaining different raspberry-based products. When rehydration is needed for foods direct consumption or use in composite products, a comprehensive Evaluation of anthocyanin degradation. Table 3 shows monomeric anthocyanins content and also on thermal degradation. This ACY decrease was particularly relevant.


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Thermal and enzymatic degradation of raspberry anthocyanins by George Vasilios Daravingas Download PDF EPUB FB2

SUMMARY— The thermal degradation of anthocyanin pigments of black raspberries as influenced by pH, oxygen, sugars and their degradation products were studied.

The degradation of the major anthocyanin component (cyanidin‐3‐digluco‐side), the total isolated pigments and the pigment in the natural berry juice was retarded as the pH by: Knowledge of anthocyanin degradation kinetics, including reaction order, rate constant (k) and half-life (t 1/2) is very important to predict food quality loss during thermal processing.

Therefore, kinetic studies are much needed in order to minimize the undesired degradation, and to Cited by: 3.

SUMMARY— The thermal degradation of anthocyanin pigments of black raspberries as influenced by pH, oxygen, sugars and their degradation products were studied.

The degradation of the major. The degradation of the major anthocyanin component, cyanidin- 3-diglucoside, was further studied in buffered model systems of various pH values at 50°C. As the pH of the medium decreased the anthocyanin stability increased.

The same was true for total crude pigment and the anthocyanin Author: George Vasilios Daravingas. Thermal and enzymatic degradation of raspberry anthocyanins methods were carried out on the pigments\ud and their products after specific chemical degradations.\ud The degradation of the major anthocyanin component, cyanidin-\ud 3-diglucoside, was further studied in buffered model systems of\ud various pH values at 50°C.

Nitrogen\ud. Thermal degradation kinetics of anthocyanins and visual color (Hunter a* value) of blood orange juice were studied at selected temperatures (°C).

Results indicated that both the thermal degradation of anthocyanin and visual color all followed first-order reaction kinetics, and they could be expressed by Arrhenius equation.

Kinetics and thermal degradation of anthocyanin content has been investigated in three raspberry varieties in connection with the variety itself, the sucrose content and the temperature.

The values of the rate constant for the first order reaction, and the activation parameters have been calculated. Experiment has been carried 88, 98, and °C. Thermal degradation behaviour of anthocyanin extract of Clitoria ternatea flower (CTAE) at temperature range of 5– C were studied.

Effects of benzoic acid and light on its stability at storage temperature were also investigated. Thermal degradation of CTAE showed first order kinetics only at 70, and C.

At 5 C, it showed a gradual decrease in color intensity to about 85% over the. Anthocyanin pigments readily degrade during thermal processing which can have a dramatic impact on colour quality and may also affect nutritional properties.

This review attempts to summarize some important aspects of anthocyanin degradation during thermal processing. Anthocyanin contents during storage decreased in time- and temperature-dependent manners. Linear regression confirmed that the degradation of anthocyanins in blackberry juice and concentrate followed by a first-order reaction (Fig.

3, Fig. 4).The values of the first-order model are given in Table t 1/2 values at the same temperatures were calculated asand days. The degradation of this pigment as a function of pH was studied for two polyphenol oxidases isolated from the fruit pulp on DEAE‐cellulose with chlorogenic acid, D (+) catechine and pyrocatechol substrates.

The decoloration was influenced by the anthocyanin structure at different pH and by the nature of the quinone obtained by enzymatic.

The activation energies for the degradation of raspberry anthocyanins, L ‐ascorbic acid and total phenolics wereand kJ /mol, respectively. Higher activation energies (– kJ /mol) found for color loss indicates, this reaction is more sensitive to.

Title THERMAL AND ENZYMATIC DEGRADATION OF RASPBERRY ANTHOCYANINS Abstract approved t^ j _, 7 (Major professor) The elucidation of the structure of the red pigments of the black raspberries. Monger variety, was achieved. The components of the pigment of the berries were (a) cyanidinglucoside, (b) cyanidin The blackberry juice showed the highest content of anthocyanins with g/L (two times less in the roselle extracts and 12 times less in the blood orange juice).

The rate constant for anthocyanin degradation and isothermal kinetic parameters were calculated according to. Degradation is primarily caused by oxidation, cleavage of covalent bonds or enhanced oxidation reactions due to thermal processing. Thermal degradation of anthocyanins can result in a variety of species depending upon the severity and nature of heating.

Fig. 1 shows the degradation of anthocyanins and formation of various intermediate compounds. enzymatic maceration, despite initial high anthocyanins content, the content of total anthocyanins is reduced after the second pasteurization to the approximate value as that in batches subjected to a single-stage enzymatic maceration.

Key words: anthocyanins, raspberry, extraction, pectin preparation. Raspberry juices treated with two commercial pectinase preparations lost almost 20% of their total anthocyanin pigments; losses were related to both concentration of enzyme and time of treatment.

Analysis of individual anthocyanins showed differences between the enzymes. Thermal degradation kinetics of anthocyanin and visual colour (tristimulus L, a and b values) of plum puree were studied at selected temperatures (50–90C) for a residence time of 20min.

The degradation kinetics of total anthocyanins in blueberry (Vaccinium myrtillus) juice were studied during thermal processing by treatment at selected temperatures (60− °C) and combined high pressure−temperature processing (− MPa, 40− °C).

Anthocyanin stability was also studied for several of these treatments during storage at 4, 25, and 40 °C. The aim of this study was prevention of thermal degradation of blackberry juice anthocyanins through sugar addition. Blackberry juice samples were prepared without and with addition of 10% of different sugars (sucrose, fructose, glucose and trehalose), and heated at 50, 70 and 90 8C for 1 and 2 h.

Since degradation of anthocyanins. During thermal degradation, the lowest rate of degradation for total anthocyanin ( × 10⁻⁴ min⁻¹), C3G ( × 10⁻⁴ min⁻¹), and P3G ( × 10⁻⁴ min⁻¹) were observed at.Anthocyanins (also anthocyans; from Greek: ἄνθος (anthos) "flower" and κυάνεος / κυανοῦς kyaneos/kyanous "dark blue") are water-soluble vacuolar pigments that, depending on their pH, may appear red, purple, blue or plants rich in anthocyanins include the blueberry, raspberry, black rice, and black soybean, among many others that are red, blue, purple, or black.Isothermal – isobaric degradation of anthocyanins in strawberry and raspberry paste followed first order kinetics.

Both temperature and pressure demonstrated accelerating effects on anthocyanin degradation. The estimated reaction rate constants showed a relatively high temperature dependence, while their pressure dependence appeared limited.